Nanomaterials possess superior advantages due to their special geometries, higher surface area, and unique mechanical, optical, and physicochemical properties. Their characteristics make them great contributors to the development of many technological and industrial sectors. Therefore, novel nanomaterials have an increasing interest in many research … - Download [PDF]
Nanomaterials possess superior advantages due to their special geometries, higher surface area, and unique mechanical, optical, and physicochemical properties. Their characteristics make them great contributors to the development of many technological and industrial sectors. Therefore, novel nanomaterials have an increasing interest in many research …
The attractive structural properties of aerogel put together aerogel as a superior material for battery, solar cell, fuel cell and supercapacitor applications. Therefore, the application of aerogels to energy conversion and storage devices is summarized in three major categories inorganic, organic and composite aerogels.
5.1.2 2D/2D Heterostructures for Advanced Batteries. In the application of 2D/2D heterostructures as the electrode materials for advanced batteries, the exposed high-area surface of the 2D nanostructures could ensure intimate contact with both the electrolyte and the current collector, which can improve the kinetics of desired ion transfer.
Recently, other 2D atomic crystals, and their possible applications in catalysis, have attracted considerable interest 10.Many of these layered materials (for example MoS 2 and WS 2) have long ...
Lithium–sulfur (Li–S) batteries are regarded as promising candidates for high-energy storage devices because of their high theoretical energy density (2600 Wh kg −1).However, their practical applications are still hindered by a multitude of key challenges, especially the shuttle effect of soluble lithium polysulfides (LiPSs) and the sluggish sulfur redox kinetics.
Nanosystems, operating at the nanoscale, have garnered significant attention due to their unique properties and potential applications in various fields, such as chemical, catalytic, energy, and environmental applications [207], [3], [5], [7], [139], [101].For example, nanozymes, a type of nanosystem, have been highlighted for their importance in in-vitro testing and …
The emergence of various electronic devices and equipment such as electric vehicles and drones requires higher energy density energy storage devices. Lithium–sulfur batteries (LSBs) are considered the most promising new-generation energy storage system owing to its high theoretical specific capacity and energy density. However, the severe shuttle …
More importantly, many advanced in-situ characterization technologies and electronic structure analyses have been combined to study the "black box" of the catalytic process, which promotes the practical application of Li-S batteries entering a new stage. In this review, instead of summarizing recent achievements in catalyst materials and ...
Important structural changes in the size and morphology occur during the preparation of nanocatalysts, but also when they are applied under certain conditions (e.g. during the course of a chemical reaction).The structural changes are illustrated schematically in Figure 1.3.Materials have a higher specific surface when their particle size is reduced.
The ultimate goal of catalysis research is the implementation of zero-emission technologies for energy, chemicals and environmental applications. Promising materials developed by research must ...
Zinc–air batteries (ZABs) are gaining attention as an ideal option for various applications requiring high-capacity batteries, such as portable electronics, electric vehicles, and renewable energy storage. ZABs offer advantages such as low environmental impact, enhanced safety compared to Li-ion batteries, and cost-effectiveness due to the abundance of zinc. …
The theoretically proposed graphene/single-walled carbon nanotube (G/SWCNT) hybrids by placing SWCNTs among graphene planes through covalent C–C bonding are expected to have extraordinary physical properties and promising engineering applications. However, the G/CNT hybrids that have been fabricated differ greatly from the proposed …
1 Introduction. The market for portable electronic devices and electric vehicles has been dominated by lithium-ion batteries (LIBs). However, current LIBs have limited energy densities and are unable to meet the increasing demand, while their energy densities are also approaching their theoretical limits of around 300 Wh kg –1. [1, 2] In addition, the uneven …
Post-lithium metal||S batteries show promise for practical applications, but limited understanding of cell parameters and sulfur electrocatalytic conversion hampers progress.
The exploration of anode materials is important for the development of K-ion batteries (KIBs) as the promising alternative of Li-ion batteries. The large ionic radius of K ions greatly constrains the selection of anode materials. We propose the pores with appropriate size in structure can promote the storage of K ions.
This paper mainly explores the different applications of nanomaterials in new energy batteries, focusing on the basic structural …
The applications of copper (Cu) and Cu-based nanoparticles, which are based on the earth-abundant and inexpensive copper metal, have generated a great deal of interest in recent years, especially in the field of catalysis. The possible modification of the chemical and physical properties of these nanoparticles using different synthetic strategies and conditions …
16 · Hard carbon, a prominent member of carbonaceous materials, shows immense potential as a high-performance anode for energy storage in batteries, attracting significant …
A Li-S cell generally consists of a cathode with sulfur (S) as the active material, a lithium metal anode, a separator, and a liquid organic electrolyte [13, 14].The S 8 active material involves a 16-electrons transfer reaction (S 8 + 16Li + + 16e − ⇋ 8Li 2 S, Fig. 1 a), enabling Li-S battery to output a high theoretical capacity of 1674 mAh g −1 [15], which is much higher than …
This is a Special Issue entitled "Synthesis and Application of Nanocatalytic Materials". Coordinating the increased energy demand and the rising environmental crisis is an extremely important issue in contemporary society. The development of state-of-the-art nanocatalytic materials is crucial to achieving efficient and clean energy systems ...
Recently, HEOs have been explored for the applications of electrode materials for Li/Na ion batteries, solid electrolytes, and electrode materials for Li-sulfur battery. These applications demand the materials for different properties, such as high capacity, either high electronic conductivity, or high ionic conductivity, etc.
Owning to unsaturated coordination environment, quantum size effect and metal-support interaction, single- or dual-atom metal sites, such as Mn, Fe, Co, Ni, Cu, Zn, Mo, Ru, Rh, Pd, Ag, Sn, Ir, Pt, Au, Bi, and Er coordinated with nonmetallic elements such as O, N, P, and S, exhibit different electronic configurations, which endow them with high catalytic performances …
Here we demonstrate a non-noble metal high-entropy alloy grown on Cu foam (NNM-HEA@CF) as a self-supported catalytic electrode for nickel-hydrogen gas (Ni-H 2) batteries. Experimental and theoretical …
Current opportunities, future challenges, and outlooks for the application of multiscale materials (NMs, sub-nano, cluster, and atomically dispersed materials) in catalysis, energy and environmental protection, etc. are summarized and outlined. ... NiMn-LDH, NiAl-LDH, etc.) can be used in sensors, electrochemical catalysts, and battery ...
The application of MNPs in electrocatalysis delivers interesting electrochemical properties due to their reduced size and high surface area-to-volume ratio, improved electrode conductive interface and allows metal–ligand interactions to be explored. 96 One of the major drawbacks of using naked MNPs as catalysts is that they cannot be recycled from reactive …
This article provides a comprehensive overview of the up-to-date progress of high-index-facet and high-surface-energy nanocrystals, ranging from a fundamental understanding of the materials and the underpinning …
Nanostructure processing has had an incredible impact on the development of new and improved Li rechargeable batteries. The reduced dimensions of nanomaterials can shorten the diffusion time of Li ions, where t = L 2 /D (t is the time constant for diffusion, L is diffusion length and D is diffusion constant) [17].This facilitates fast kinetics and high charge …
Abstract Polymer solid-state lithium batteries (SSLB) are regarded as a promising energy storage technology to meet growing demand due to their high energy density and safety. Ion conductivity, interface stability and battery assembly process are still the main challenges to hurdle the commercialization of SSLB. As the main component of SSLB, poly(1,3 …
Catalysts are one of the fundamental pillars of the chemical industry and have been widely applied in chemical synthesis, energy storage and conversion, biomedical applications, and environmental remediation [1,2,3].Nanomaterials, which have nano-size intriguing physicochemical properties compared with their bulk materials and excellent …
The increasing demand for wearable electronic devices necessitates flexible batteries with high stability and desirable energy density. Flexible lithium–sulfur batteries (FLSBs) have been increasingly studied due to their high theoretical energy density through the multielectron chemistry of low-cost sulfur. However, the implementation of FLSBs is challenged …
The current review provides important insights into the nanocatalysis as a cutting-edge strategy for favorable cathode pre-lithiation and builds a bridge between academic research and industrial applications of nanocatalytic cathode pre-lithiation for lithium-ion …
The application of carbon nanotubes (CNTs) as supporting materials for manganese oxides composite catalyst (CMnCs) was reported by Sun and Liu [178]. The materials were obtained through activating the commercial CNTs in acidic KMnO 4 solutions. The permanganate solution may oxidize the outer wall of CNTs and partially transform the layer into ...
This Special Issue focuses on the application of nanocatalysts in the field of energy and environment. In addition to producing clean energy efficiently, nanocatalysts …
Nanoscience has opened up new possibilities for Li rechargeable battery research, enhancing materials'' properties and enabling new chemistries. Morphological …
Lithium–sulfur batteries with high energy capacity are promising candidates for advanced energy storage. However, their applications are impeded by shuttling of soluble polysulfides and sluggish conversion …
The development of efficient, stable, and low-cost bifunctional catalysts for the hydrogen evolution/oxidation reaction (HER/HOR) is critical to promote the application of hydrogen gas batteries in large scale energy storage systems. Here we demonstrate a non-noble metal high-entropy alloy grown on Cu foam (NNM-HEA@CF) as a self-supported catalytic …