Clearly, the as-prepared perovskite thin film shows a pronounced (008) lattice plane peak, and the peak intensity gradually decreases as the laser fluence increases from 0.030 to 0.113 J cm −2 ... - Download [PDF]
Clearly, the as-prepared perovskite thin film shows a pronounced (008) lattice plane peak, and the peak intensity gradually decreases as the laser fluence increases from 0.030 to 0.113 J cm −2 ...
The 2D/3D perovskite thin films are prepared by depositing a HABr precursor on the 3D bulk perovskite thin film, followed by thermal annealing for in situ conversion.
A promising strategy to address both the morphology of perovskite films and charge transport issues is the utilization of SAMs as interfacial modification layers. In particular, employing hole-selective SAMs to passivate the surface of NiO x has emerged as an effective approach for enhancing the performance of PSCs. Hole-selective SAMs offer ...
This protocol below describes the specific steps to prepare electron transporting layer (ETL) via chemical bath deposition, prepare perovskite film via two-step method, …
A fs-pulsed laser beam with a wavelength of 800 nm (Coherent, repetition rate: 80 MHz and pulse width: 100 fs) was focused on the perovskite thin film by an objective lens with a numerical ...
Additive engineering is another effective method for enhancing the properties of perovskite films 41,53,70,71,72, which may significantly affect crystallization kinetics, film quality, and the ...
9 perovskite discs, and the research presented by Huang et al. presents dielectric relaxation in a cadmium-based 1D organic-inorganic halide perovskite. Moreover, Huang et al. and Burley et al. present two research articles related to perovskite-like organic-inorganic frameworks. T he particular perovskite materials have given a significant
Spray deposition of perovskite thin films has emerged as a prominent research focus within the realm of thin film fabrication methodologies [23].Zhi et al. fabricated a thin film of perovskite …
However, perovskite films often exhibit abundant intrinsic defects, which can limit the efficiency of perovskite-based optoelectronic devices by acting as carrier recombination centers. Thus, an understanding of defect chemistry in lead halide perovskites assumes a prominent role in further advancing the exploitation of perovskites, which, to a ...
This work offers comprehensive insights into the use of guanidine-based additives to achieve high-quality perovskite films and subsequently state-of-the-art MA-free PSCs. Conflict of Interest. The authors declare no conflict of …
In 2022, Wang et al. used multifunctional aminoguanidine hemisulfate to modify perovskite films for defect passivation, and finally achieved a PCE of 10.1 ... In 2 S 3 /CsPbIBr 2 /C 60 /CuSCN/C carbon-based all-inorganic perovskite battery. The current density–voltage (J-V), quantum efficiency (QE), and energy band structure of perovskite ...
Considering the complexity of the current perovskite battery preparation process and the expensive materials, it is obviously time-consuming, laborious and inefficient to directly adopt the experimental exploration method, so it is the most convenient way to theoretically explore the most qualified M/G-Electrode and use it to guide the ...
In the last decade, organic-inorganic halide perovskites having the chemical formula ABX 3 (A is a monovalent cation, B represents a divalent cation from group IV-A and X represents a halogen anion) have been extensively studied because of their promising applications in photovoltaic and light-emitting devices [[16], [17], [18], [19]].These materials …
2.2 Structure and Operational Principle of Perovskite Photovoltaic Cells. The structure and operational principle of perovskite photovoltaic cells are shown in Fig. 2, and the operation process of perovskite devices mainly includes four stages. The first stage is the generation and separation of carriers, when the photovoltaic cell is running, the incident …
With this in mind, this paper will analyze the principle as well as the state-of-art performances for the solar battery based on perovskite. To be specific, the brief history of the development of ...
1 · The solution containing perovskite precursors is directly coated or spin-coated on the substrate, and after annealing treatment, a perovskite layer can be formed; the two-step solution method first prepares an intermediate product, and then converts it into a perovskite layer through a reaction, which can better control the quality and ...
Metal halide perovskites with the general formula ABX 3 (where A is a cation, B is a divalent metal ion and X is a halide) are a class of semiconductors that have the potential to deliver cheaper ...
However, perovskite films often exhibit abundant intrinsic defects, which can limit the efficiency of perovskite-based optoelectronic devices by acting as carrier recombination centers. Thus, an understanding of defect …
We present a design strategy for fabricating ultrastable phase-pure films of formamidinium lead iodide (FAPbI 3) by lattice templating using specific two-dimensional (2D) perovskites with FA as the cage cation.When a pure FAPbI 3 precursor solution is brought in contact with the 2D perovskite, the black phase forms preferentially at 100°C, much lower than …
The optical and electrical properties of the perovskite film, such as light absorption, carrier diffusion length, and charge transport, are all directly affected by the film …
Perovskite solar cells (PSCs) provide attractive prospects for the photovoltaic industry, but the harsh preparation conditions and stability of perovskite materials are still the biggest obstacles to the industrialization of PSCs. This review paper compares the differences in composition and working principle between dye-sensitized solar cells and PSC. It also reviews …
Starting from 2015, there are some attempts to explore the application of perovskite materials in lithium-ion batteries. For example, in our previous work, CH 3 NH 3 PbBr 3 and CH 3 NH 3 PbI 3 prepared by a hydrothermal method were used as anode materials [30], with first discharge specific capacities of 331.8 and 43.6 mAh g −1 obtained, respectively. …
Forming high-quality perovskite films is the most critical process in the manufacture of high-performance large-scale PSCs and PSMs. ... Moreover, this printing method demonstrates extremely low material waste and good scalability. The working principle is precisely depositing a minuscule ink volume onto the substrate from the nozzle. According ...
Hybrid improper ferroelectricity can effectively avoid the intrinsic chemical incompatibility of electronic mechanism for multiferroics. Perovskite superlattices, as theoretically proposed hybrid ...
Perovskite solar cells (PSCs) with evaporated gold (Au) electrodes have shown great efficiencies, but the maturity of the technology demands low-cost and scalable alternatives to progress towards ...
This review focuses on principles of XRD techniques and their application for the characterization of the perovskite thin-film microstructure. ... are discussed, including the need for simulating diffraction patterns. Applications of XRD techniques in characterizing perovskite thin films are demonstrated for both three-dimensional and layered ...
1 Introduction. While market-dominating single-junction silicon photovoltaics (PVs) are approaching their theoretical efficiency limit of around 29%, [] power conversion efficiencies (PCEs) of up to 33.7% [] have been recently demonstrated for monolithic perovskite/silicon tandem solar cells (TSCs). Hybrid lead halide perovskite solar cells (PSCs) …
Guo et al. investigated the changes in MAPbI 3 perovskite films by XRD plots at the temperature range of 40, 50, 60, 70, and 80 °C. The higher the temperature, the fewer the middle phases, the more orientated towards the planar planes of (110) and (220), and the purer the perovskite film.
2.3 Edge States of 2D Perovskite. The edge states are localized electronic states that exist at the edges of 2D perovskite structures, which exhibit different optical and …
The unique properties of perovskites, such as fast exciton dissociation and large diffusion lengths, together with the shallow trap states caused by impurities, reduces to a large extent the …
Considering the voltage-matching principle of two units, the open-circuit voltage (V oc) of the solar cell unit must surpass the redox reaction potential of the corresponding battery unit ...