DOI: 10.1016/j.cej.2023.145446 Corpus ID: 261015955; Polyurethane/LLZTO solid electrolyte with excellent mechanical strength and electrochemical property for Advanced lithium metal battery - Download [PDF]
DOI: 10.1016/j.cej.2023.145446 Corpus ID: 261015955; Polyurethane/LLZTO solid electrolyte with excellent mechanical strength and electrochemical property for Advanced lithium metal battery
The uneven plating/stripping of lithium ions leads to the growth of lithium dendrites and battery safety risks, hindering the further development and commercial application of lithium metal batteries (LMBs). Constructing solid-state electrolyte (SSE) systems with high mechanical strength and low flammability is among the most effective ...
extraordinary mechanical strength as high- performance lithium-ion battery anodes Haiping Jia 1, Xiaolin Li 1, Junhua Song 1, Xin Zhang 2, Langli Luo 3, Yang He 3, Binsong Li 4, Yun Cai 5,
The severe volumetric expansion and poor conductivity of silicon when used as anode in lithium-ion batteries present challenges in maintaining the stability of electrochemical performance. Herein, the binding between silicon nanoparticles and carbon nanotubes (CNTs) is achieved by the utilization of sodium alginate (SA), which is then strengthened by the …
The development of thin solid-state electrolyte with high ionic conductivity and mechanical strength is of great importance for the high-performance all-solid-state lithium–sulfur battery. However, the state-of-the-art solid polymer electrolyte suffers from poor ionic conductivity and a high thickness but inferior mechanical strength. Herein, a thin laminar composite solid …
However, the mechanical strength of SN will suffer from a significant decrease when complexing with lithium salts, which results in excessive plastic and even liquid-like behavior and hence impedes its further application as a self-supporting electrolyte film in solid lithium metal batteries (LMBs).
Separators in lithium-ion batteries (LIBs) play an important role for battery safety, so stable electrochemical performance and high mechanical strength of separators will always be of interest. On the basis of the fact that polydopamine (PDA) nanoparticles found in mussel have a strong adhesion ability, biomaterial surface nanoparticles modification methods are developed …
The resulting electrolyte film exhibited outstanding extensibility, with 220% strain and ultimate tensile strength of 5.12 MPa. Moreover, it demonstrated excellent stability in static and electrochemical cycles, thanks to its high lithium-ion …
Succinonitrile (SN)-based electrolytes provide an attractive candidate for solid electrolytes because of their high room-temperature ionic conductivity and favorable interfacial contact with electrodes. However, the mechanical strength of SN will suffer from a significant decrease when complexing with lithium salts, which results in excessive plastic and even liquid …
Polyimide (PI) nanofiber membrane prepared by electrospinning technique exhibits poor mechanical strength for the slippage of fibers, which limits it applied into lithium ion battery (LIB). In this study, we are devoted to promoting the macro mechanical strength of PI nanofiber membrane by inhibiting the slippage among the fibers.
PDA modified commercial paper separator engineering with excellent lithiophilicity and mechanical strength for lithium metal batteries. Author links open overlay panel Mei-Ling Zhou, Ze ... the development of advanced separators with excellent compatibility to lithium anode and high mechanical strength would be effective to eliminate the non ...
Higher energy density is an endless pursuit for energy storage devices. Common anode materials for lithium-ion batteries, such as graphite based on the insertion mechanism, are limiting further development of long-endurance batteries [1].Li metal anode with the highest specific capacity (3860 mAh g − 1) and the lowest potential (−3.04 V versus standard hydrogen …
This paper focuses on the mechanical response and thermal runaway phenomena caused by external mechanical stress of lithium-ion batteries at different states of charge (SOC). The results show that the SOC affects the mechanical strength as well as the temperature of the battery under external stress. When stress is applied to the cell, the ...
The mechanically hard phase and ionically conductive phase endow suitably designed block copolymer electrolytes (BCPEs) with the "Janus" property, thus providing the opportunity to decouple the trade-off between mechanical strength and ionic conductivity by controlling the phase-separated structures. The conductivity of BCPEs is predominantly …
Since the first rechargeable lithium battery (lithium ion battery) was commercialized by Sony Corporation in 1991, significant efforts have focused on improving the battery''s life cycle and safety. 2, 8 One prevalent approach is …
The microstructure of the electrode and its mechanical properties are important factors affecting the performance of lithium batteries. Calendering is one of the most important aspects that affect the microstructure and mechanical response of lithium battery electrodes. Discrete element method was employed to establish a lithium battery electrode model that …
Thin separators with robust mechanical strength are undoubtedly prime choice to make lithium-based batteries more reliable and safer. This review focuses mainly on recent developments in thin separators for lithium-based batteries, lithium-ion batteries (LIBs) and lithium-sulfur (Li-S) batteries in particular, with a detailed introduction of ...
Due to high mechanical strength, excellent chemical and electrochemical stability, polyethylene (PE) and polypropylene (PP) porous membranes have become the most widely used separator for lithium-ion batteries (LIB) [].However, the polyolefin separator will melt below 160 °C, limiting its further use in energy storage systems, especially in electric vehicles …
In this work, the frictional properties of various polymer binders were studied using atomic force microscopy to enhance the mechanical integrity of the silicon (Si) anode for lithium-ion batteries…
With the frequent occurrence of safety accidents in traditional liquid electrolyte-based lithium-ion batteries and the urgent demand for high-energy-density lightweight electrical devices, All-solid-state lithium metal batteries ... The resulting CSEs exhibit high mechanical strength (20.0 MPa), t Li+ (0.46), and specific capacity ...
renewed ininterest has lithium metal unstable electrodeposition of Li during operation obstructed progress in practical battery applications. While deformation mechanics likely play a key role in Li''s mechanical stability as an anode material, reports of Li''s mechanical properties vary widely, per-haps due to variations in testing procedures.
The first rechargeable lithium battery was designed by Whittingham (Exxon) and consisted of a lithium-metal anode, a titanium disulphide (TiS 2) cathode ... and have sufficient mechanical strength to avoid rupturing during charging and discharging cycles over the range of operational temperatures; (2) ...
Potential applications of graphene-based materials in practical lithium batteries are highlighted and predicted to bridge the gap between the academic progress and industrial manufacture, thereby paving the way for accelerating the development of graphene-based material as well as lithium battery industry. ... mechanical strength, chemical ...
The high porosity, mechanical stability and enhanced ionic conductivity of the membrane improved the electrochemical performance of the lithium-ion battery. Experimental Materials and methods
Asymmetric lithium battery systems require secure and tamper-resistant sealing to prevent both accidental and intentional tampering. ... batteries using these electrolytes often exhibit low ionic conductivity or weak mechanical strength, thereby limiting their widespread use (Dhanda et al., 2022).
Since the first rechargeable lithium battery (lithium ion battery) was commercialized by Sony Corporation in 1991, significant efforts have focused on improving the battery''s life cycle and safety. 2, 8 One prevalent approach is to reduce the amount of organic solvent in the electrolyte system. Though organic solvents offer improved ion transport …
Substantial interest exists in the development of lithium-ion battery cathodes with exceptional resistance to degradation. Cathode particles fracture during charging and discharging due to dimensional changes that accompany varying lithium occupancy. Fracture …
Despite advancements in silicon-based anodes for high-capacity lithium-ion batteries, their widespread commercial adoption is still hindered by significant volume expansion during cycling, especially at high active mass loadings crucial for practical use. ... In order to confirm the origin of the enhanced mechanical strength after modified SPS ...
As an indispensable part of the lithium-ion battery (LIB), a binder takes a small share of less than 3% (by weight) in the cell; however, it plays multiple roles. The binder is decisive in the slurry rheology, thus influencing the coating process and the resultant porous structures of electrodes. ... The mechanical strength of the film enhances ...
Separator is an essential component in lithium-ion batteries (LIBs), which greatly affects the electrochemical performance of the battery. ... The separator must be strong enough to withstand the strain of the winding operation when mounting the battery. Mechanical strength is typically defined in terms of tensile strength in both the machine ...
The discovery of stable transition metal oxides for the repeated insertion and removal of lithium ions 1, 2, 3 has allowed for the widespread adoption of lithium-ion battery (LIB) cathode materials in consumer electronics, such as cellular telephones and portable computers. 4 LIBs are also the dominant energy storage technology used in electric vehicles. 5 An increase …
The supramolecular lithium ion conductor utilizes orthogonally functional H-bonding domains and ion-conducting domains to create a polymer electrolyte with unprecedented toughness (29.3 MJ m −3...
Since its discovery in 1987, it has attracted considerable interest due to its impressive physical and chemical properties. 117 Properties like large surface area, superior mechanical strength, high electrical conductivity, good …
The current collector fracture failure of lithium-ion batteries (LIBs) occurs during its winding production process frequently, and the consequent damages are usually large, but little research has been conducted …
H hierarchical porous CNT@Si@C microspheres are constructed as anodes for Li-ion batteries, enabling both high electrochemical performance and excellent mechanical strength, and provides insights into the design of electrode materials for other batteries. Porous structured silicon has been regarded as a promising candidate to overcome pulverization of …
With the potential to dramatically increase energy density compared to conventional lithium ion technology, lithium metal solid-state batteries (LMSSB) have attracted significant attention. However, little is known about the mechanical properties of Li. The purpose of this study was to characterize the elastic and plastic mechanical properties and creep …